STATEMENT OF HAZARDOUS NATURE: HAZARDOUS ACCORDING TO WORKSAFE AUSTRALIA CRITERIA

SUPPLIER
Company: Tantec Ltd
Address: P O Box 65 404; Mairangi Bay; Auckland 1330; New Zealand
Telephone: +64 9 415 8774
Emergency Tel: 0800 429243
Fax:: +64 9 415 8775
 

Product Name: CAS RN No(s): UN Number: Packaging Group: Dangerous Goods Class: Subsidiary Risk: Hazchem Code: Poisons Schedule Number:

Tantec Tecmate 100 None None None None None None NZ S4

USE: Preservative.

PHYSICAL DESCRIPTION/PROPERTI ES
APPEARANCE: Clear alkaline liquid with a weak odour; mixes with water.
 

Boiling Point (deg C): Melting Point (deg C): Vapour Pressure (kPa): Specific Gravity: Flash Point (deg C): Lower Explosive Limit (%): Upper Explosive Limit (%): Solubility in Water (g/L):

Not available Not available Not available Not available Not applicable Not applicable Not applicable Miscible

INGREDIENTS

NAME sodium dimethyldithiocarbamate sodium hydroxide water

CAS RN 128-04-1 1310-73-2 7732-18-5

% 30-60 0.5max . 30-60

EYE: The material may be irritating to the eye, with prolonged contact causing inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis.

SKIN: The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic). This form of dermatitis is often characterised by skin redness (erythema) and sweling (oedema) which may progress to vesiculation, scaling and thickening of the epidermis. Histologically there may be intercellular oedema of the spongy
layer (spongiosis) and intracellular oedema of the epidermis.

INHALED: Not normally a hazard due to non-volatile nature or product. The mist is discomforting to the upper respiratory tract.

EYE: If this product comes in contact with the eyes: Immediately hold the eyes open and wash with fresh running water. Ensure irrigation under the eyelids by occasionally lifting upper and lower lids. If pain persists or recurs seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

SKIN: If product comes in contact with the skin: Immediately remove all contaminated clothing, including footwear (after rinsing with water). Wash affected areas thoroughly with water (and soap if available). Seek medical attention in event of irritation

INHALED: If fumes or combustion products are inhaled: Remove to fresh air. Lay patient down.  Keep warm and rested. If breathing is shallow or has stopped, ensure clear airway and apply resuscitation. Transport to hospital or doctor.

• Animal studies suggest that contact dermatitis and thyroid hyperplasia rnay occur following exposure.
• These compounds do not have the cholinergic properties of structurally related carbamate insecticides.
• The usual measures for gut and skin contamination are recommended for large doses.
• Some thiocarbamates are structurally similar to disulfiram and may cause the characteristically unpleasant alcohol response in a small number of patients. Disulfuram/ alcohol type reactions may last for several hours; they may respond to fluids, oxygen and analgesics. Dysrhythmias may occur and patients with serious reactions should have cardiac monitoring.
• Precautions should be taken to prohibit intake of alcohol for 10 days.
• Fats, oils and lipid solvents must not be consumed as they may enhance absorption.

Sodium hydroxide
TLVC: 2 mg/m3
ES Peak: 2 mg/m3
OES STEL: 2 mg/m3
IDLH level: 250 mg/m3

EYE: Safety glasses with side shields; or as required, Chemical goggles. Contact lenses pose a special hazard; soft lenses may absorb irritants and all lenses concentrate them.

HANDS/FEET: Wear chemical protective gloves. eg. PVC gloves with barrier cream. Wear safety footwear.

OTHER: Overalls. Eyewash unit.

RESPIRATOR: Selection of the Class and Type of respirator will depend upon the level of breathing zone contaminant and the chemical nature of the contaminant. Protection Factors (defined as the ratio of contaminant outside and inside the mask) may also be important.
 

Breathing Zone  Level ppm (volume) ----------------------   1000   1000   5000   5000 10000

Maximum Protection Factor ----------------------   10   50   50 100 100  100+

Half-face Respirator ---------------------- -AUS P - Airline* - - -

Full-Face Respirator ---------------------- - -AUS P - -2P -3P Airline**

*- Continuous Flow.   ** - Continuous-flow or positive pressure demand.

The local concentration of material, quantity and conditions of use determine the type of personal protective equipment required. For further information, consult site specific CHEMWATCH data (if available), or your Occupational Health and Safety Advisor.

SUITABLE CONTAINER: Polyethylene or polypropylene container. Plastic carboy Plastic drum. Polyliner drum.
Packing as recommended by manufacturer. Check all containers are clearly labelled and free from leaks.

STORAGE INCOMPATIBILITY: Avoid storage with oxidisers and acids.

STORAGE REQUIREMENT: Store in original containers. Keep containers securely sealed. Store in a cool, dry, well-ventilated area. Store away from incompatible materials and foodstuff containers. Protect containers against physical damage and check regularly for leaks. Observe manufacturer's storing and handling recommendations

TRANSPORTATION: No restrictions.

MAJOR SPILLS: Minor hazard. Clear area of personnel. Alert Fire Brigade and tell them location and nature of hazard. Control personal contact by using protective equipment as required. Prevent spillage from entering drains or water ways. Contain spill with sand, earth or vermiculite. Collect recoverable product into labelled containers for recycling. Absorb remaining product with sand, earth or vermiculite and place in appropriate containers for disposal. Wash area and prevent runoff into drains or waterways. If contamination of drains or waterways occurs, advise emergency services.

DISPOSAL: Recycle wherever possible or consult manufacturer for recycling options. Consult State Land Waste Management Authority for disposal. Bury residue in an authorised landfill. Recycle containers where possible, or dispose of in an authorised landfill.

AUSTRALIAN POISONS INFORMATION CENTRE
24 HOUR SERVICE             :- 13 11 26
POLICE OR FIRE BRIGADE    :- 000    (exchange):-1 100

NEW ZEALAND POISONS INFORMATION CENTRE
Dunedin  -(03)479 1200  (Normal Hours), (03)474 0999 (Emergency)