TANTEC TECMATE 196
(DICHLOROPHENE)

ChemWatch Material Safety Data Sheet 12426
Date of issue: Thu 8-Oct-1998

Quick access to sections:
IDENTIFICATION
ACUTE HEALTH EFFECTS
CHRONIC HEALTH EFFECTS
FIRST AID
ADVICE TO DOCTOR
PRECAUTIONS FOR USE
ENGlNEERING CONTROLS
PERSONAL PROTECTION
STORAGE AND TRANSPORT
SPILLS AND DISPOSAL
FIRE/EXPLOSION HAZARD
CONTACT
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IDENTIFICATION

STATEMENT OF HAZARDOUS NATURE: HAZARDOUS ACCORDING TO WORKSAFE AUSTRALIA CRITERIA

SUPPLIER
Company: Tantec Ltd
Address: P O Box 65 404; Mairangi Bay; Auckland 1330; New Zealand
Telephone: +64 9 415 8774
Emergency Tel: 0800 429243
Fax:: +64 9 415 8775
 
Product Name:
CAS RN No(s):
UN Number:
Packaging Group:
Dangerous Goods Class:
Subsidiary Risk:
Hazchem Code:
Poisons Schedule Number:
Dichlorophene
97-23-4
2811
III
6.1(b)
None
2XE
S6

USE: An anthelmintic (worm treatment) used in the treatment of infection caused by tapeworms (Diphyllobothrium latum and Taenia saginata) and dwarf tapewonn (Hymenolepsis nana). Also used in the treatment of infection by pork tapeworm (T. solium). Usually administered by mouth as tablets. Also used against animal ringworrn, as a fungicide and as a germicide in
soaps. The use of dichlorophene in cosmetics and toiletries is restricted in various jurisdictions. Also used to prevent fungal and bacterial deterioration of cotton and woollen textiles, paper products, rug backings, cutting oils and canvas lawn and beach furniture.

PHYSICAL DESCRIPTION/PROPERTI ES
APPEARANCE: White crystalline solid; does not mix with water.  Slight phenolic odour and saline taste.
 
Boiling Point (deg C):
Melting Point (deg C):
Vapour Pressure (kPa):
Specific Gravity:
Flash Point (deg C):
Lower Explosive Limit (%):
Upper Explosive Limit (%):
Solubility in Water (g/L):
Not available
177-178
Not available
Not available
Not applicable
Not applicable
Not applicable
Immiscible

INGREDIENTS
NAME
dichlorophene
CAS RN %
>98



ACUTE HEALTH EFFECTS
SWALLOWED:

EYE: The material may be irritating to the eye, with prolonged contact causing inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis.

SKIN: The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic). This form of dermatitis is often characterised by skin redness (erythema) and sweling (oedema) which may progress to vesiculation, scaling and thickening of the epidermis. Histologically there may be intercellular oedema of the spongy
layer (spongiosis) and intracellular oedema of the epidermis.

INHALED: Not normally a hazard due to non-volatile nature or product. The mist is discomforting to the upper respiratory tract.



CHRONIC HEALTH EFFECTS: Principal routes of exposure are usually by inadvertent ingestion of excess drug and inhalation of dust. Despite the structural similarity with hexachlorophene no evidence exists that cross-sensitivities occur which give rise to allergic contact dermatitis. The substance may induce photosensitivity. [Sigma/Aldrich]
 
 
 



FIRST AID
SWALLOWED: If poisoning occurs, contact a doctor or Poisons Inforrnation Centre. If swallowed do NOT induce vomiting. Give a glass of water.

EYE: If this product comes in contact with the eyes: Immediately hold the eyes open and wash with fresh running water. Ensure irrigation under the eyelids by occasionally lifting upper and lower lids. If pain persists or recurs seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

SKIN: If product comes in contact with the skin: Immediately remove all contaminated dothing, including footwear (after rinsing with water). Wash affected areas thoroughly with water (and soap if available). Seek medical attention in event of irritation.

INHALED:  If dust is inhaled, remove to fresh air. Encourage patient to blow nose to ensure clear breathing passages. Rinse mouth with water. Consider drinking water to remove dust from throat. If irritation or discomfort persists seek medical attention.



ADVICE TO DOCTOR: Dichlorophene is contra-indicated in the presence of impaired liver function and in conditions in which purgation is undesirable, such as the last few months of pregnancy, in acute fevers or in severe heart disease.


PRECAUTIONS FOR USE:
EXPOSURE STANDARDS: No exposure limits set by NOHSC or ACGIH. Dusts not otherwise classified, as inspirable dust; ES TWA: 10 mg/m3.


ENGlNEERING CONTROLS: General exhaust is adequate under normal operating conditions. Local exhaust ventilation may be required in specific drcumstances.


PERSONAL PROTECTION

EYE: Safety glasses with side shields; or as required, Chemical goggles. Contact lenses pose a special hazard; soft lenses may absorb irritants and all lenses concentrate them.

HANDS/FEET: Rubber gloves.

OTHER: Overalls. Eyewash unit.

RESPIRATOR:
 
Maximum
Protection Factor
----------------------
  10 x ES
  50 x ES
  50 x ES
100 x ES
100 x ES
100+ 
Half-face
Respirator
----------------------
P1
Air-line*
Air-line**
-
-
-
Full-Face
Respirator
----------------------
-
-
P2
P3
Air-line*
Air-line**
Powered Air
Respirator
----------------------
PAPR-P1
-
PAPR-P2
-
-
PAPR-P3
*- Negative pressure demand.   ** - Continuous-flow.

The local concentration of material, quantity and conditions of use determine the type of personal protective equipment required. For further information, consult site specific CHEMWATCH data (if available), or your Occupational Health and Safety Advisor.



STORAGE AND TRANSPORT:as recommended by manufacturer. Check that containers are clearly labelled. Plastic confiner.

SUITABLE CONTAINER: Polyethylene or polypropylene container. Plastic carboy Plastic drum. Polyliner drum.
Packing as recommended by manufacturer. Check all containers are clearly labelled and free from leaks.

STORAGE INCOMPATIBILITY: Avoid reaction with oxidising agents Avoid strong acids, bases. Be sure container is tightly closed when not in use.

STORAGE REQUIREMENT: Store in original containers. Keep containers securely sealed. Store in a cool, dry, well-ventilated area. Store away from incompatible materials and foodstuff containers. Protect containers against physical damage and check regularly for leaks. Observe manufacturer's storing and handling recommendations

TRANSPORTATION: Class 6 - Poisonous (toxic) substances shall not be loaded in the same vehide or packed in the same freight container with:

Class 1 - Explosives;
Class 3 - Flammable liquids (where the flammable liquid is nitromethane);
Class 5.1 - Oxidising agents (where the poisonous substances are capable of igniting and burning)
Class 5.2 - Organic peroxides (where the poisonous substances are capable of igniting and buming)-
Foodstuff and foodstuff empties.


SPILLS AND DISPOSAL
MINOR SPILLS:  Remove all ignition sources. Clean up all spills immediately. Avoid contact with skin and eyes. Control personal contact by using protective equipment. Use dry clean up procedures and avoid generating dust. Place in a suitable labelled container for waste disposal.

MAJOR SPILLS:      Clean up all spills immediately. Wear protective clothing, safety glasses, dust mask, gloves. Secure load if safe to do so. Bundle/ collect recoverable product. Use dry clean up procedures and avoid generating dust. Vacuum up. Water may be used to prevent dusting. Collect remaining material in containers with covers for disposal. Flush spill area with water.

DISPOSAL: Recycle wherever possible. Special hazard may exist - specialist advice may be required. Consult manufacturer for recycling options. Consult State Land Waste Management Authonty for disposal. Bury or incinerate residue at an approved site. Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed. Puncture containers to prevent re-use and bury at an authorised landfill.



FIRE/EXPLOSION HAZARD:  Solid which exhibits difficult combustion or is difficult to ignite. Avoid generating dust, particularly clouds of dust in a confined or unventilated space. Dust may forrn an explosive mixture with air, and any source of ignition, i.e. flame or spark, will cause fire or explosion. Dry dust can be charged electrostatically by turbulence, pneumatic
transport, pouring, in exhaust ducts and during transport. Build-up of electrostatic charge may be prevented by grounding. Decomposes on heating and produces toxic fumes of chlorides..


CONTACT
AUSTRALIAN POISONS INFORMATION CENTRE
24 HOUR SERVICE             :- 13 11 26
POLICE OR FIRE BRIGADE    :- 000    (exchange):-1 100

NEW ZEALAND POISONS INFORMATION CENTRE
Dunedin  -(03)479 1200  (Normal Hours), (03)474 0999 (Emergency)



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